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The Microwave Spectra and Molecular Structure of Phosphorus and Arsenic Trichloride
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1950
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Microwave SpectroscopyInorganic ChemistryMicrowave SpectraEngineeringPhysicsNatural SciencesSpectroscopyApplied PhysicsArsenic TrichlorideSpectra-structure CorrelationPure Rotational SpectraChemistryMicrowave RegionSpectroscopic PropertyDistance P–cl
The pure rotational spectra of PCl3 and AsCl3 have been observed in the microwave region, and the observed fine structure has been partially explained. The distance P–Cl is 2.043±0.003A and the angle Cl–P–Cl is 100° 6′±20′. The distance As–Cl is 2.161±0.004A and the angle Cl–As–Cl is 98° 25′±30′.