The primary fragmentation step of isoxazole upon electron impact. A correlation with photochemistry

Abstract

Abstract Three isomeric compounds, I, II and III, were prepared and their mass spectra recorded. Comparisons of the spectra showed that the fragmentation of I proceeds only by way of II, and that II itself is transformed in part to III upon electron impact. It is suggested that selective ionization of each one of the two isolated functional groups in II may afford two isomeric radical ions, II a and II b . A possible interrelation to the photochemistry of these compounds is also discussed.