When Cu4I4 cubane meets Cu3(pyrazolate)3 triangle: dynamic interplay between two classical luminophores functioning in a reversibly thermochromic coordination polymer

Shun‐Ze Zhan, Mian Li, Xiao‐Ping Zhou, Jun‐Hao Wang, Jurong Yang, Dan Li

Chemical Communications · 2011 · 103 citations · 22 references

Concepts

Abstract

A supramolecular dual emissive system incorporating two classical copper(I)-cluster-based luminophores, namely, Cu(4)I(4) and Cu(3)Pz(3) (Pz = pyrazolate), is reported. The targeted luminescent coordination polymer exhibits reversible thermochromism spanning from green to orange-red.

References

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