Concepedia

Direct mono-insertion of isocyanides into terminal alkynes catalyzed by rare-earth silylamides

Kimihiro Komeyama, Daisuke Sasayama, Tomonori Kawabata, Katsuomi Takehira, Ken Takaki

Chemical Communications · 2004 · 53 citations · 23 references

DOI

Concepts

Abstract

Rare-earth silylamide complexes, Ln[N(SiMe3)2]3 (Ln = Y, La, Sm, Yb), effectively catalyzed the coupling reaction of isocyanides with both aliphatic and aromatic terminal alkynes under mild conditions.

References

23

Novel <i>Z</i>-Selective Head-to-Head Dimerization of Terminal Alkynes Catalyzed by Lanthanide Half-Metallocene Complexes

Masayoshi Nishiura, Zhaomin Hou, Yasuo Wakatsuki et al. · Journal of the American Chemical Society · 2003 · 217 citations

, , +15

Homoleptic Lanthanide Amides as Homogeneous Catalysts for Alkyne Hydroamination and the Tishchenko Reaction

M.R. Burgstein, Helga Berberich, Peter W. Roesky · Chemistry - A European Journal · 2001 · 183 citations

, , +16

Catalytic oligomerization of terminal alkynes by lanthanide carbyls (.eta.5-C5Me5)2LnCH(SiMe3)2 (Ln = Y, La, Ce)

Hero J. Heeres, Jan H. Teuben · Organometallics · 1991 · 149 citations · Full text

, , +13

Synthesis of Allyl Cyanamides and <i>N</i>-Cyanoindoles via the Palladium-Catalyzed Three-Component Coupling Reaction

Shin Kamijo, Yoshinori Yamamoto · Journal of the American Chemical Society · 2002 · 138 citations

, , +8

Exceptional Rate Enhancements and Improved Diastereoselectivities through Chelating Diamide Coordination in Intramolecular Alkene Hydroaminations Catalyzed by Yttrium and Neodymium Amido Complexes

Young Kwan Kim, Tom Livinghouse · Angewandte Chemie International Edition · 2002 · 137 citations

, , +8