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Novel Metallacycle Complexes from Bis(oxazolinyl)pyridine−Rhodium(I) Species and Diynes
34
Citations
9
References
2002
Year
X-ray CrystallographyInorganic ChemistryChemical EngineeringEngineeringNatural SciencesCoordination ComplexNovel Metallacycle ComplexesNew TypesMetallacycle ComplexesMolecular ComplexOrganometallic CatalysisChemistryInorganic Synthesis
The reaction of [Rh(coe)2Cl]2 (coe = cis-cyclooctene), bis(oxazolinyl)pyridine (pybox), and diynes (O(CH2C⋮CCO2Me)2 and PhC⋮CCH2OCH2C⋮CCO2Me) gave new types of metallacycle complexes, which were analyzed by X-ray crystallography and showed catalytic activity for cycloaddition of diynes and several alkynes.
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