The First Metallacyclopentadiene(Alkyne) Complexes and Their Discrete Isomerization to η⁴-Bound Arenes: The Missing Link in the Prevalent Mechanism of Transition Metal Catalyzed Alkyne Cyclotrimerizations, as Exemplified by Cyclopentadienylcobalt

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTThe First Metallacyclopentadiene(Alkyne) Complexes and Their Discrete Isomerization to η4-Bound Arenes: The Missing Link in the Prevalent Mechanism of Transition Metal Catalyzed Alkyne Cyclotrimerizations, as Exemplified by CyclopentadienylcobaltRainer Diercks, Bruce E. Eaton, Stefan Gürtzgen, Satish Jalisatgi, Adam J. Matzger, Rachel H. Radde, and K. Peter C. VollhardtView Author Information Department of Chemistry, University of California at Berkeley, and the Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley, California 94720-1460 Cite this: J. Am. Chem. Soc. 1998, 120, 32, 8247–8248Publication Date (Web):July 29, 1998Publication History Received21 May 1998Published online29 July 1998Published inissue 1 August 1998https://pubs.acs.org/doi/10.1021/ja981766qhttps://doi.org/10.1021/ja981766qrapid-communicationACS PublicationsCopyright © 1998 American Chemical SocietyRequest reuse permissionsArticle Views1118Altmetric-Citations85LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (2)»Supporting Information Supporting Information SUBJECTS:Aromatic compounds,Hydrocarbons,Kinetics,Ligands,Metals Get e-Alerts