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Equilibria between pyranoses and furanoses. II. Aldoses
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1972
Year
Equilibrium SolutionBioorganic ChemistryAldo-keto ReductaseBiochemistryAldehyde DehydrogenaseNatural SciencesPhysiologyAnomerio ProtonsSecondary MetaboliteOrganic ChemistryChemistryMetabolismMedicineBiophysicsDeuterium Oxide Solution
The proton magnetic resonance spectra of the aldopentoses and aldohexoses were determined in deuterium oxide solution. The signals of the anomerio protons of the two furanose and the two pyranose forms were located; the identification of these signals is discussed. The proportions of the four forms in equilibrium solution were determined.