Structural changes and the metal-non-metal transition in supercritical fluids

Abstract

Energy-dispersive x-ray diffraction (XD), small-angle x-ray scattering (SAXS) and x-ray absorption fine-structure (XAFS) measurements for metallic fluids up to the supercritical region were carried out using synchrotron radiation. We obtained the structure factor S(k) and the pair distribution functions g(r) for expanded fluid Hg from the liquid to the dense vapour region including the metal-non-metal (M-NM) transition region in the density range from 13.6 to 1.9 g cm-3 by means of XD measurements at SPring-8 in Japan. The density variations of the interatomic distance (r1) and coordination number (N1) obtained are discussed in relation to the M-NM transition in fluid Hg. To investigate structural change in the semiconductor-metal (SC-M) transition in expanded fluid Se, XD measurements, at SPring-8, and XAFS measurements, at the European Synchrotron Radiation Facility (ESRF) in France, were carried out at high temperatures and high pressures. It was found that the twofold-coordinated chain structure is preserved and contraction of the covalent bond occurs on the SC-M transition. XAFS measurements for dense Se vapour near the critical point were also carried out to study how dimers in the rarefied vapour condense to the metallic fluid. SAXS measurements were carried out to obtain information on the density fluctuation of fluid Se near the critical point. On the basis of the structural data obtained by XD, XAFS and SAXS measurements for fluid Se, we discuss how the density fluctuation affects the local structure and electronic properties of fluid Se near the critical point.