Physical Review · 1923 · 11 citations · 0 references
Natural SciencesPhysicsOpticsPhotonicsSpectroscopyAtomic IonizationEmission SpectroscopyPhotoelectric EffectQuartz
Long wave-length limit for photo-electric emission from caesium vapor.---Using a special quartz tube and taking precautions to avoid photo-electric emission from the electrodes, a narrow beam of nearly monochromatic light of gradually decreasing wave-length, was focused on the hot caesium vapor, and it was found that above 3220 A the emission was zero, between 3220 and 3145 A the emission changed linearly because of the width of the slit used, and below 3145 A the emission was practically constant. The mean, 3180 A, is taken as the critical wave-length. This is evidently identical with the convergence wave-length 3184.28 A, which is related to the ionization potential ${V}_{i}$ according to the equation ${V}_{i}=\frac{\mathrm{hc}}{e{\ensuremath{\lambda}}_{i}}$. Therefore the separation of an electron from a caesium atom requires the same amount of work whether produced by an impinging electron or by absorption of light.