Concepedia

Spectroelectrochemistry at ultrahigh vacuum: in situ monitoring of electrochemically generated species by X-ray photoelectron spectroscopy

Alasdair W. Taylor, Qiu Fulian, Ignacio J. Villar‐García, Peter Licence

Chemical Communications · 2009 · 65 citations · 20 references

DOI

Concepts

Abstract

The electrochemical reduction of Fe(III) to Fe(II) in the ionic liquid (IL) mixture of 1-ethyl-3-methylimidazolium ethylsulfate, [C(2)C(1)Im][EtOSO(3)], and 1-butyl-3-methylimidazolium tetrachloroferrate (III), [C(4)C(1)Im][Fe(III)Cl(4)], was monitored in situ by X-ray photoelectron spectroscopy (XPS).

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