Concepedia

Palladium-Catalyzed Alkyl-Alkyl Cross-Coupling Reaction of 9-Alkyl-9-BBN Derivatives with Iodoalkanes Possessing β-Hydrogens

Tatsuo Ishiyama, Shigeru Abe, Norio Miyaura, Akira Suzuki

Chemistry Letters · 1992 · 231 citations · 5 references

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Abstract

Abstract 9-Alkyl-9-BBN derivatives undergo the cross-coupling reaction with primary iodoalkanes to give the coupling products in fairly good yields in the presence of a catalytic amount of Pd(PPh3)4 and K3PO4.

References

5

Palladium-catalyzed inter- and intramolecular cross-coupling reactions of B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with 1-halo-1-alkenes or haloarenes. Syntheses of functionalized alkenes, arenes, and cycloalkenes via a hydroboration-coupling sequence

Norio Miyaura, Tatsuo Ishiyama, Hirotomo Sasaki et al. · Journal of the American Chemical Society · 1989 · 547 citations

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Mechanism of thermal decomposition of trans-diethylbis(tertiary phosphine)palladium(II). Steric effects of tertiary phosphine ligands on the stability of diethylpalladium complexes

Fumiyuki Ozawa, Takashi Ito, Akio Yamamoto · Journal of the American Chemical Society · 1980 · 137 citations

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Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones

Tatsuo Ishiyama, Norio Miyaura · Tetrahedron Letters · 1991 · 115 citations

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New developments in palladium catalysed cross coupling: The coupling of alkyl iodides with alkyl Grignard reagents

Paul Laurence Castle, David A. Widdowson · Tetrahedron Letters · 1986 · 71 citations

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A re-examination of the palladium-catalyzed cross coupling of alkyl iodides with alkyl Grignard reagents

Kaixu Yuan, William J. Scott · Tetrahedron Letters · 1989 · 50 citations

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