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Explaining the Flocculation of Hassi Messaoud Asphaltenes in Terms of Structural Characteristics of Monomers and Aggregates
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2009
Year
Highway PavementEngineeringOrganic ChemistryChemistrySpectra-structure CorrelationAsphalt BinderGeotechnical EngineeringPetroleum ChemistryRheologyAnalytical ChemistryAsphaltMaterials SciencePhysical ChemistryNanoclaySmall Asphaltene ClustersStructural CharacteristicsNatural SciencesSpectroscopyLdi-tof MassX-ray DiffractionHassi Messaoud AsphaltenesPetroleum GeochemistryPetroleum EngineeringSpectroscopic Method
X-ray diffraction, liquid 1H and solid 13C nuclear magnetic resonance (NMR), Raman, Fourier transform infrared (FTIR), laser desorption/ionization-time of flight (LDI-TOF) mass and fluorescence spectroscopy have been used to determine structural properties of asphaltenes obtained from Hassi Messaoud crude oil. While liquid 1H- and 13C-NMR, IR, and LDI-TOF mass and fluorescence spectroscopy allow the determination of the chemical composition and structure of single asphaltene molecules, X-ray diffraction and Raman spectroscopy make it possible to asses parameters characterizing small asphaltene clusters. The proposed characterization of petroleum asphaltenes affords information that leads to better understanding of asphaltene flocculation conditions.