Concepedia

Allylic rearrangements during the rhodium-catalysed reactions of 2-allyloxybenzylamines and 2-(N-allyl-N-benzylamino)benzylamine

Eva M. Campl, W. R. JACKSON, Quentin J. McCubbin, A. E. TRNACEK

Journal of the Chemical Society Chemical Communications · 1994 · 22 citations · 2 references

DOI

Concepts

Abstract

Reactions of 2-allyloxybenzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.

References

2

Example of thermodynamic control in palladium-catalyzed allylic alkylation. Evidence for palladium-assisted allylic carbon-carbon bond cleavage

Ylva Nilsson, Pher G. Andersson, J.‐E. BAECKVALL · Journal of the American Chemical Society · 1993 · 112 citations

, , +7

Nucleophilic substitution at the central allyl carbon atom of a (.pi.-allyl)platinum complex

Kouichi Ohe, Hideki Matsuda, Tsumoru Morimoto et al. · Journal of the American Chemical Society · 1994 · 74 citations

, , +6