Reactivity of α-trifluoromethanesulfonyl esters, amides and ketones: Decarboxylative allylation, methylation, and enol formation

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

John F. Hartwig, Levi M. Stanley · Accounts of Chemical Research · 2010 · 711 citations

Natural Sciences, Chemistry, Catalysis +16

Mild Electrophilic Trifluoromethylation of Carbon‐ and Sulfur‐Centered Nucleophiles by a Hypervalent Iodine(III)–CF₃ Reagent

Iris Kieltsch, Patrick Eisenberger, Antonio Togni · Angewandte Chemie International Edition · 2006 · 520 citations

Natural Sciences, Chemistry, Catalysis +9

Dissociation constants of uncharged and monovalent cation acids in dimethyl sulfoxide

I. M. Kolthoff, M. K. Chantooni, Sadhana Bhowmik · Journal of the American Chemical Society · 1968 · 401 citations

Natural Sciences, Biochemistry, Chemistry +11

Pd‐Catalyzed Synthesis of ArSCF₃ Compounds under Mild Conditions

Georgiy Teverovskiy, D. Surry, Stephen L. Buchwald · Angewandte Chemie International Edition · 2011 · 355 citations · Full text

Natural Sciences, Chemistry, Medicinal Chemistry +10

Copper‐Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF₃ and Elemental Sulfur

Chao Chen, Yan Xie, Lingling Chu et al. · Angewandte Chemie International Edition · 2012 · 305 citations

Natural Sciences, Chemistry, Analytical Chemistry +7