Physical Review Letters · 2006 · 97 citations · 18 references
Natural SciencesPhysicsCondensed Matter PhysicsQuantum MechanicsTransport PhenomenaMagnetism In SolidsMolecular Quantum MechanicsQuantum TunnelingSpintronic MaterialsSpintronicsAnisotropyMolecular MagnetsQuantum TransportQuantum Tunneling DynamicsSingle-molecule MagnetsSpin Selection RulesSpin TransportSpin-orbit Selection Rules
We demonstrate that transport spectroscopy of single molecular magnets shows signatures of quantum tunneling at low temperatures. We find current and noise oscillations as a function of bias voltage due to a weak violation of spin-selection rules by quantum tunneling processes. The interplay with Boltzmann suppression factors leads to fake resonances with temperature-dependent position which do not correspond to any charge excitation energy. Furthermore, we find that quantum tunneling can completely suppress transport if the transverse anisotropy has a high symmetry.
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Magnetic bistability in a metal-ion cluster
Roberta Sessoli, Dante Gatteschi, Andréa Caneschi et al. · Nature · 1993 · 4.3K citations
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High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
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