Concepedia

First Synthesis and Structure of Hexavalent Organic σ-Perselenurane Species (λ6-Selane): Bis(2,2′-biphenylylene)difluoroperselenurane [12-Se-6(C4F2)]

Soichi Sato, Hiroshi Arakawa, Ernst Horn, Naomichi Furukawa

Chemistry Letters · 1998 · 12 citations · 6 references

DOI

Concepts

Abstract

Abstract Bis(2,2′-biphenylylene)selenurane (1; λ4-selane) reacts with xenon difluoride to give bis(2,2′-biphenylylene)difluoroperselenurane, [12-Se-6(C4F2)] (2; λ6-selane), which was analyzed by single crystal X-ray diffraction.

References

6

N.M.R. spectra of the<i>X<sub>n</sub>AA′ X<sub>n</sub>′</i>type

Robin K. Harris, C.M. Woodman · Molecular Physics · 1966 · 78 citations

, , +7

HYPERVALENT ORGANIC DERIVATIVES OF TELLURIUM AND SELENIUM*

Dieter Hellwinkel · Annals of the New York Academy of Sciences · 1972 · 36 citations

, , +5

Dynamic NMR studies on the solution-state structure and the pseudorotation of bis(2,2′-biphenylylene)selenurane and tellurane

Satoshi Ogawa, Soichi Sato, Tomoki Erata et al. · Tetrahedron Letters · 1992 · 23 citations

, , +5

Selenium Oxide Tetrafluoride

Konrad Seppelt · Angewandte Chemie International Edition in English · 1974 · 22 citations

Isolation and structure of bis(2,2′-biphenylylene)dichloro- and -difluoropertelluranes, [12-Te-6(C4X2), X = Cl, F] (λ6-tellane)

Soichi Sato, Takahiro Yamashita, Ernst Horn et al. · Tetrahedron · 1997 · 16 citations

, , +2