Concepedia

A Bowl-Shaped Phosphine as a Ligand in Palladium-Catalyzed Suzuki−Miyaura Coupling of Aryl Chlorides:  Effect of the Depth of the Bowl

Hidetoshi Ohta, Makoto Tokunaga, Yasushi Obora, Tomohiro Iwai, Tetsuo Iwasawa, Tetsuaki Fujihara, Yasushi Tsuji

Organic Letters · 2006 · 93 citations · 21 references

DOI

Concepts

Abstract

[reaction: see text] Bowl-shaped phosphine ligands were found to be highly effective in Suzuki-Miyaura coupling of unactivated aryl chlorides, in which the depth of the bowl affected the catalytic activity considerably.

References

21

Catalysts for Suzuki−Miyaura Coupling Processes:  Scope and Studies of the Effect of Ligand Structure

Timothy E. Barder, Shawn D. Walker, Joseph R. Martinelli et al. · Journal of the American Chemical Society · 2005 · 1.8K citations

, , +16

Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions

Adam F. Littke, Chaoyang Dai, Gregory C. Fu · Journal of the American Chemical Society · 2000 · 1.6K citations

, , +16

Modified (NHC)Pd(allyl)Cl (NHC = <i>N</i>-Heterocyclic Carbene) Complexes for Room-Temperature Suzuki−Miyaura and Buchwald−Hartwig Reactions

Nicolas Marion, Oscar Navarro, Jianguo Mei et al. · Journal of the American Chemical Society · 2006 · 907 citations

, , +13

A Convenient and General Method for Pd-Catalyzed Suzuki Cross-Couplings of Aryl Chlorides and Arylboronic Acids

Adam F. Littke, Gregory C. Fu · Angewandte Chemie International Edition · 1998 · 702 citations

, , +10

A Versatile Catalyst for Heck Reactions of Aryl Chlorides and Aryl Bromides under Mild Conditions

Adam F. Littke, Gregory C. Fu · Journal of the American Chemical Society · 2001 · 690 citations

, , +14