MAGNETRON SPUTTERING DEPOSITION OF POLYCRYSTALLINE <font>CrN</font>/<font>ZrN</font> SUPERLATTICE COATINGS

Mao Wang, Jinfang Zhang, Q. X. Liu, D. J. Li

Surface Review and Letters · 2006 · 10 citations · 9 references

Concepts

Abstract

The influence of substrate rotary speed, species of reaction gases and flows on nanoindentation, nanoscratch fracture, and residual stress were explored on reactive sputtered nanoscale CrN / ZrN multilayered coatings. Hardness and critical fracture load as high as 32 GPa and 85 mN with desirable compressive stress were achieved for this model. A proper percentage of NH 3 in N 2 reaction gas was also proved to be of benefit to synthesize high-hard and fracture-resistant CrN / ZrN coatings. The low-angle XRD patterns provided the layer modulation period of the coatings. A marked polycrystallite of two-cubic NaCl phase CrN + ZrN as well as probably hexagonal Cr 2 N with small modulation period corresponded to the enhanced mechanical properties.

References

9