New Insights on the High-Temperature Nanostructure Evolution of SiOC and B-Doped SiBOC Polymer-Derived Glasses

Abstract

SiOC and SiBOC polymer-derived glasses show a complex nanostructure in which nanocrystalline β-SiC and sp 2 C coexists with nanoclusters of amorphous SiO 2 or SiO 2 −B 2 O 3 and with mixed silicon oxycarbide and boron oxycarbide units. The characterization of the nanostructure is performed with a multiple technique approach on SiOC and SiBOC glasses before and after HF etching. The acid attack dissolves the silica-based nanoclusters and allows indirect information on their size and amount to be obtained. By increasing the pyrolysis temperature from 1200 up to 1500 °C the oxide clusters grow in size and amount in both SiOC and SiBOC glasses. Compared to the B-free SiOC glass, SiBOC is more easily etched and develops higher porosity and larger pore size. Boron has also an important effect on the ordering of the sp 2 C phase: it leads to thicker sp 2 C nanocrystals. This effect is remarkable because it starts at low temperature (1500 °C) compared to the usual temperature, 1800 °C, reported in the literature for different forms of nanocrystalline carbon. Raman analysis of SiBOC glasses pyrolyzed at 1500 °C clearly shows the presence of the D‘ band at 1617 cm -1 . From this experimental result it is postulated that B enters into the graphene layers forming BC 3 units. Finally, the shift toward lower wavenumbers of the Raman spectra recorded on SiOC and SiBOC glasses after etching seems to reveal a high compressive stress acting along the basal sp 2 C planes of the graphite nanocrystals.