Journal of the American Chemical Society · 2009 · 717 citations · 20 references
Natural SciencesMaterials EngineeringMaterials ScienceNanomaterialsPolymer ChemistryPolymer EngineeringPolymer StructureRedox ChemistryRedox ProcessesRedox ReactionsRedox-active MaterialsSupramolecular PolymersBlock Copolymer MicellesBlock Copolymer Self-assemblyMicellesMild Reaction ConditionsPolymeric MicellesRedox PolymersRedox-responsive MaterialsRedox-responsive Polymers
A block copolymer with diselenide bonds in the polymer backbone was reported. This block copolymer was capable of forming micellar aggregates that were responsive to redox stimuli. Compared with other redox responsive aggregates, this type of diselenide-containing block copolymer aggregates could be responsive to both oxidants and reductants even in a solution with a very low concentration under mild conditions.
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