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A gas-phase Raman study of the dissociation of selenium tetrachloride and the vibrational spectrum and molecular structure of selenium dichloride
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1970
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Molecular SpectroscopyEngineeringPhysicsNatural SciencesSpectroscopyApplied PhysicsPhysical ChemistrySelenium DichlorideNon-linear Triatomic MoleculeGas-phase Raman StudyQuantum ChemistryChemistrySelenium TetrachlorideGaseous Selenium DichlorideSpectroscopic PropertySpectra-structure CorrelationSpectroscopic Method
Selenium tetrachloride is shown by gas-phase laser Raman spectroscopy to be fully dissociated in the vapour to selenium dichloride and chlorine, the vibrational spectrum of gaseous selenium dichloride being entirely consistent with that expected for a non-linear triatomic molecule.