Concepedia

Chemistry of acetylenic ethers 103 Stereospecific addition of Grignard compounds to 1‐alkynyl sulfides in the presence of copper(I) halide

P. Vermeer, Chris de Graaf, J. Meijer

Recueil des Travaux Chimiques des Pays-Bas · 1974 · 43 citations · 5 references

DOI

Concepts

Abstract

Abstract Excellent yields of vinylic sulfides R 1 R 2 CCHS‐CH 3 are produced in a cis ‐addition reaction, from 1‐alkynyl sulfides R 1 CCS‐CH 3 and Grignard compounds R 2 MgX under the influence of copper(I) halide in tetrahydrofuran.

References

5

Organocopper(I) Compounds and Organocuprates in Synthesis

J. F. NORMANT · Synthesis · 1972 · 309 citations

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On phenylcopper

G. Costa, A. Camus, Larissa Carla Pinheiro Gatti et al. · Journal of Organometallic Chemistry · 1966 · 98 citations

Synthese stereospecifique and reactivite d' organocuivreux vinyliques

J. F. NORMANT, M. Bourgain · Tetrahedron Letters · 1971 · 96 citations

, , +11

Chemistry of acetylenic ethers 74: 1‐(dialkylamino)‐1‐alkynes from 1‐alkoxy‐1‐alkynes

P. P. Montijn, E. Harryvan, L. Brandsma · Recueil des Travaux Chimiques des Pays-Bas · 1964 · 18 citations

, , +4

Chemistry of acetylenic ethers. Part 89: The reaction of organolithium compounds with 1‐alkynyl ethers

J. G. A. Kooyman, H. P. G. Hendriks, P. P. Montijn et al. · Recueil des Travaux Chimiques des Pays-Bas · 1968 · 17 citations

, , +5