Concepedia

Monomeric Tris(η<sup>2</sup>‐pyrazolato)Lanthanoid Complexes with the Bulky 3,5‐Di(<i>tert</i>‐butyl)pyrazolato Ligand

Joanna E. Cosgriff, Glen B. Deacon, Bryan M. Gatehouse, Holger Hemling, Herbert Schumann

Angewandte Chemie International Edition in English · 1993 · 59 citations · 11 references

DOI

Concepts

Abstract

The reaction of lanthanoids, Hg(C6F5)2, and tBu2pz (pz = pyrazolate) in THF provided the first monomeric lanthanoid complexes of type 1 with solely chelating pz ligands. The structure on the right depicts the neodymium complex.

References

11

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

R. D. Shannon · Acta Crystallographica Section A · 1976 · 63.5K citations

, , +16

X-ray scattering factors computed from numerical Hartree–Fock wave functions

D. T. Cromer, J. B. Mann · Acta Crystallographica Section A · 1968 · 3.5K citations

, , +13

Three- and four-co-ordinate, hydrocarbon-soluble-aryloxides of scandium, yttrium, and the lanthanoids; X-ray crystal structure of tris(2,6-di-t-butyl-4-methylphenoxo)scandium

Peter B. Hitchcock, Michael F. Läppert, Anirudh Singh · Journal of the Chemical Society Chemical Communications · 1983 · 163 citations

, , +14

Organoamido- and Aryloxo-Lanthanoids. II. Preparation of Tris(2,6-diphenylphenoxo)-lanthanoid(III) Complexes and the X-Ray Structures of Low-Coordinate [Yb(O-2,6-Ph2C6H3)3] Containing an Intramolecular Chelate Yb…π-Arene Interaction, and [Yb(O-2

S. Nickel, P. MACKINNON, ERT Tiekink · Australian Journal of Chemistry · 1990 · 99 citations

Organouranium complexes of pyrazole and pyrazolate. Synthesis and x-ray structures of U(C5Me5)2Cl2(C3H4N2), U(C5Me5)2Cl(C3H3N2), and U(C5Me5)(C3H3N2)2

Charles Eigenbrot, Kenneth N. Raymond · Inorganic Chemistry · 1982 · 88 citations

, , +13