Concepedia

Generation of the <i>triangulo</i>‐Group MO<sup>V</sup>‐η‐S<sub>2</sub> in the “Condensation” of [Mo<sup>VI</sup>O<sub>2</sub>S<sub>2</sub>]<sup>2</sup> to [MoO<sub>2</sub>S<sub>2</sub>(S<sub>2</sub>)<sub>2</sub>]<sup>2</sup>

Walter Rittner, Achim Müller, Axel Neumann, Wolfgang Bäther, Ramesh Chandra Sharma

Angewandte Chemie International Edition in English · 1979 · 39 citations · 4 references

DOI

Concepts

Abstract

Formation of the η‐disulfidomolybdenum( V ) group by a novel intramolecular redox process has been observed on warming aqueous solutions of dithiomolybdate( VI ). The structure of the anion in the orange‐red crystals of (1) was determined by X‐ray methods. equation image

References

4

Thio and seleno compounds of the transition metals with the do configuration

E. Diemann, Achim Müller · Coordination Chemistry Reviews · 1973 · 218 citations

, , +10

Eine einfache Darstellung der binären Metall‐Schwefel‐Cluster [Mo<sub>3</sub>S<sub>13</sub>]<sup>2−</sup> und [Mo<sub>2</sub>S<sub>12</sub>]<sup>2−</sup> aus MoO<sub>4</sub><sup>2−</sup> in praktisch quantitativer Ausbeute

Achim Müller, Ram Gopal Bhattacharyya, B. PFEFFERKORN · Chemische Berichte · 1979 · 115 citations

, , +12

[(S<sub>2</sub>)<sub>2</sub>Mo(S<sub>2</sub>)<sub>2</sub>Mo(S<sub>2</sub>)<sub>2</sub>]<sup>2−</sup>, a Novel Complex Containing Only S Ligands and a MoMo Bond

Achim Müller, Wulf‐Otto Nolte, Bernt Krebs · Angewandte Chemie International Edition in English · 1978 · 74 citations

, , +15

Optically Active Polyvinyl Compounds with Chirality in the Main Chain

Günter Wulff, Karl Zabrocki, Johann Hohn · Angewandte Chemie International Edition in English · 1978 · 41 citations

, , +13