Concepedia

[(S<sub>2</sub>)<sub>2</sub>Mo(S<sub>2</sub>)<sub>2</sub>Mo(S<sub>2</sub>)<sub>2</sub>]<sup>2−</sup>, a Novel Complex Containing Only S Ligands and a MoMo Bond

Achim Müller, Wulf‐Otto Nolte, Bernt Krebs

Angewandte Chemie International Edition in English · 1978 · 74 citations · 6 references

DOI

Concepts

Abstract

Mo-S compounds occur in redox enzymes whose action involves electron transfer MoVI⇌MoV. In this context, interest attaches to the new complex (1), which is formed on reduction of molybdate(VI) by polysulfide ions in aqueous solution. In (1), Mo has the unusual coordination number 9.

References

6

Thio and seleno compounds of the transition metals with the do configuration

E. Diemann, Achim Müller · Coordination Chemistry Reviews · 1973 · 218 citations

, , +10

Vibrational spectra of transition metal chalcogen compounds

K. Schmidt, Achim Müller · Coordination Chemistry Reviews · 1974 · 95 citations

, , +13

The inorganic chemistry of biological processes

J.W.T. · Journal of Molecular Structure · 1975 · 80 citations

, , +9

Electron Spin Resonance of Xanthine Oxidase Substituted with Molybdenum-95

Robert C. Bray, L. S. Meriwether · Nature · 1966 · 75 citations

, , +11

Organometallic sulfur complexes. VIII. The molecular structure of a doubly sulfur-bridged dimeric complex of molybdenum(V), [C5H5MoO]2S2, containing a molybdenum-molybdenum interaction

Donald L. Stevenson, Lawrence F. Dahl · Journal of the American Chemical Society · 1967 · 50 citations

, , +13