Journal of Physics B Atomic Molecular and Optical Physics · 1996 · 23 citations · 20 references
Quantum DynamicQuantum ScienceEngineeringPhysicsMany-body Quantum PhysicComplicated DynamicsComplex ScalingNatural SciencesWave ScatteringQuantum Field TheoryApplied PhysicsAtomic PhysicsDisordered Quantum SystemComputational ChemistryQuantum ChemistryComplex Expectation ValuesElectronic StructureMany-body Problem
The definition of a norm for scattering states is reviewed particularly with respect to the method of complex scaling used to determine resonant states. The meaning of complex expectation values which result from this procedure is illustrated with a simple two-channel model. In a further example autoionizing states of helium are analysed in terms of complex expectation values which are shown to provide a sensitive tool to probe details of complicated dynamics. We also demonstrate how Lewis structures for resonances may be defined through complex expectation values.
20
Gilbert N. Lewis · Journal of the American Chemical Society · 1916 · 1.7K citations
Engineering, Altmetric Attention Score, Molecular Biology +19
Ground State of Two-Electron Atoms
C. L. Pekeris · Physical Review · 1958 · 1.1K citations
Engineering, Electron Diffraction, Computational Chemistry +17