CURIE TEMPERATURE, BIREFRINGENCE, AND PHASE-MATCHING TEMPERATURE VARIATIONS IN LiNbO3 AS A FUNCTION OF MELT STOICHIOMETRY

J. G. Bergman, A. Ashkin, A. A. Ballman, J. M. Dziedzic, H. J. Levinstein, R. G. Smith

Applied Physics Letters · 1968 · 209 citations · 4 references

Concepts

Abstract

The Curie temperature, birefringence, and phase-matching temperature of LiNbO3 are shown to vary with the stoichiometry of the melt from which the crystals are pulled. The range of melt stoichiometry, indexed by the Li/Nb mole ratio, was varied from 1.20 to 0.80. This Li/Nb variation changes the Curie temperature, refractive index for the extraordinary ray, and the phase-matching temperature by 120°C,.03, and 320°C respectively. The relevance of these changes are discussed in terms of the susceptibility of LiNbO3 to index inhomogeneities.

References

4