Publication | Closed Access
Absolute line strengths for carbon and sulfur
24
Citations
26
References
1974
Year
EngineeringAbsolute Line StrengthsAtomic Emission SpectroscopySii LinesAbsorption SpectroscopyExperimental ThermodynamicsSpectroscopic PropertyThermodynamicsPhysicsCii LinesAbsolute Transition ProbabilitiesAtomic PhysicsPhysical ChemistryQuantum ChemistryPhysicochemical AnalysisNatural SciencesSpectroscopyCarbon BlackPhotometry (Optics)
Absolute transition probabilities for 124 CI, SI, and SII lines in the range 3600-7400 \AA{}A are measured with a spectroscopic shock tube. Relative strengths of two CII lines are also determined. Mixtures of neon and ten different compounds of carbon and sulfur are heated to temperatures 8200-13000\ifmmode^\circ\else\textdegree\fi{}K at pressures (4.8-27.0) \ifmmode\times\else\texttimes\fi{} ${10}^{6}$ dyn ${\mathrm{cm}}^{\ensuremath{-}2}$. Thermodynamic and photometric variables are measured redundantly. Absolute $A$ values are determined in emission by two or more independent methods which in combination have much less than the traditional sensitivity to systematic errors in source temperature. Estimated accuracies for the more prominent visible lines are 13-30%. Results are compared with theoretical predictions, other experiments, and with quantum-mechanical sum rules.
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