Concepedia

Triple Bonding to Tin: Synthesis and Characterization of the Stannylyne Complex <i>trans</i>‐[Cl(PMe<sub>3</sub>)<sub>4</sub>WSnC<sub>6</sub>H<sub>3</sub>‐2,6‐Mes<sub>2</sub>]

Alexander C. Filippou, Peter Portius, Athanassios I. Philippopoulos, Holger Rohde

Angewandte Chemie International Edition · 2003 · 92 citations · 21 references

DOI

Abstract

Straightening out tin: The reaction of the dinitrogen complex 1 with the aryl tin(II) chloride 2 affords selectively the stannylyne complex 3. The molecular structure of 3 shows a very short WSn bond of 2.4902(8) Å and a linear coordinated tin atom (W-Sn-C=178.2(1)°). R=C6H3-2,6-Mes2, Mes=C6H2-2,4,6-Me3.

References

21

Synthesis and Characterization of 2,6-Trip<sub>2</sub>H<sub>3</sub>C<sub>6</sub>PbPbC<sub>6</sub>H<sub>3</sub>-2,6-Trip<sub>2</sub> (Trip = C<sub>6</sub>H<sub>2</sub>-2,4,6-<i>i</i>-Pr<sub>3</sub>):  A Stable Heavier Group 14 Element Analogue of an Alkyne

Lihung Pu, Brendan Twamley, Philip P. Power · Journal of the American Chemical Society · 2000 · 365 citations

, , +12

Synthesis and Characterization of a Digermanium Analogue of an Alkyne

Matthias Stender, A.D. Phillips, Robert Wright et al. · Angewandte Chemie International Edition · 2002 · 342 citations

, , +11

Synthesis and Characterization of the Monomeric Diaryls M{C<sub>6</sub>H<sub>3</sub>-2,6-Mes<sub>2</sub>}<sub>2</sub> (M = Ge, Sn, or Pb; Mes = 2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>−) and Dimeric Aryl−Metal Chlorides [M(Cl){C<sub>6</sub>H<sub>3</sub>-2,6-Mes<sub>2</sub>}]<sub>2</sub> (M = Ge or Sn)

Richard S. Simons, Lihung Pu, Marilyn M. Olmstead et al. · Organometallics · 1997 · 313 citations

, , +11

Synthesis and Characterization of 2,6-Dipp<sub>2</sub>-H<sub>3</sub>C<sub>6</sub>SnSnC<sub>6</sub>H<sub>3</sub>-2,6-Dipp<sub>2</sub> (Dipp = C<sub>6</sub>H<sub>3</sub>-2,6-Pr<sup>i</sup><sub>2</sub>):  A Tin Analogue of an Alkyne

A.D. Phillips, Robert Wright, Marilyn M. Olmstead et al. · Journal of the American Chemical Society · 2002 · 299 citations

, , +9

<i>trans</i>‐Halogeno[alkyl(aryl)carbyne]tetracarbonyl Complexes of Chromium, Molybdenum, and Tungsten —A New Class of Compounds Having a Transition Metal‐Carbon Triple Bond

Ernst Otto Fischer, Gerhard Kreis, Cornelius G. Kreiter et al. · Angewandte Chemie International Edition in English · 1973 · 245 citations

, , +6