Concepedia

Synthesis and Characterization of a Digermanium Analogue of an Alkyne

Matthias Stender, A.D. Phillips, Robert Wright, Philip P. Power

Angewandte Chemie International Edition · 2002 · 345 citations · 51 references

DOI

Concepts

Abstract

Multiple Ge−Ge bonds: The title compound, which has a trans-bent structure (see structure; Ge-Ge-C=128.67(8)°) and a short Ge−Ge bond (2.2850(5) Å), is the first stable digermanium analogue of an alkyne.

References

51

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Synthesis and Characterization of 2,6-Trip<sub>2</sub>H<sub>3</sub>C<sub>6</sub>PbPbC<sub>6</sub>H<sub>3</sub>-2,6-Trip<sub>2</sub> (Trip = C<sub>6</sub>H<sub>2</sub>-2,4,6-<i>i</i>-Pr<sub>3</sub>):  A Stable Heavier Group 14 Element Analogue of an Alkyne

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How Short is a -Ga⋮Ga- Triple Bond? Synthesis and Molecular Structure of Na<sub>2</sub>[Mes*<sub>2</sub>C<sub>6</sub>H<sub>3</sub>-Ga⋮Ga-C<sub>6</sub>H<sub>3</sub>Mes*<sub>2</sub>] (Mes* = 2,4,6-<i>i</i>-Pr<sub>3</sub>C<sub>6</sub>H<sub>2</sub>):  The First Gallyne

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