Complexes of lanthanoid salts with the crown ether cis,syn,cis-2,5,8,15,18,21-hexaoxatricyclo[20.4.0.0]hexacosane and their paramagnetically shifted nuclear magnetic resonance spectra

Graham A. Catton, Mary E. Harman, F. A. Hart, Geoffrey E. Hawkes, Gerard P. Moss

Journal of the Chemical Society Dalton Transactions · 1978 · 22 citations · 0 references

Concepts

Abstract

Lanthanoid perchlorates form complexes [M(ClO4)3(shoth)] with the title crown ether (shoth) whose n.m.r. spectra show shifts which are predominantly dipolar. The magnetic-susceptibility tensors are not axially symmetric.