Journal of the Chemical Society A Inorganic Physical Theoretical · 1970 · 55 citations · 0 references
Rare Earth MineralEngineeringSingle-crystal Raman SpectraGas-phase Raman SpectraChemistryInorganic MaterialSpectroscopic PropertyObserved FundamentalsMaterials ScienceInorganic ChemistryPhysical ChemistryFunctional MaterialsCrystallographyCrystal Structure DesignCubic FormGas PhaseSpectroscopyNatural SciencesGeochemistryAuthigenic Mineral FormationSpectroscopic MethodMineral Geochemistry
The observed fundamentals of the cubic form of As4O6(arsenolite) are unambiguously assigned from single-crystal measurements. Data are also reported for the isomorphous senarmonite (Sb4O6) which (in the mineral) contains small quantities of the orthorhombic polymorph valentinite (Sb4O6). The gas-phase Raman spectra of P4O10, P4O6, and As4O6(together with polarization data) suggest that the cage structure is retained in the gas phase.