Intramolecular benzylic C–H activation: palladium-catalyzed synthesis of hexahydromethanofluorenes - Concepedia

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Intramolecular benzylic C–H activation: palladium-catalyzed synthesis of hexahydromethanofluorenes

78

Citations

14

References

2000

Year

Marta Catellani, Elena Motti, Stefano Ghelli

Chemical Communications

Chemical EngineeringEngineeringBenzylic Methyl GroupsPalladium ComplexOrganic ChemistryOrganometallic CatalysisCatalysisMolecular CatalysisChemistryPalladium-catalyzed SynthesisC–h ActivationCatalytic Synthesis

Abstract

C–H activation of benzylic methyl groups has been realized catalytically under mild conditions through intramolecular reaction on a palladium complex.

References

	Year	Citations
Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution Bruce A. Arndtsen, Robert G. Bergman, T. Andrew Mobley, Accounts of Chemical Research Inorganic ChemistryChemical EngineeringEngineeringHomogeneous SolutionCoordination Complex	1995	1.4K
A Complex Catalytic Cycle Leading to a Regioselective Synthesis of <i>o,o</i>′‐Disubstituted Vinylarenes Marta Catellani, Franco Frignani, Armando Rangoni Angewandte Chemie International Edition in English Inorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringAlkene Metathesis	1997	697
Palladium‐Catalyzed CH Activation of Methoxy Groups: A Facile Synthesis of Substituted 6<i>H</i>‐Dibenzo[<i>b</i>,<i>d</i>]pyrans Gerald Dyker Angewandte Chemie International Edition in English	1992	240
Mechanisms of d8 organometallic reactions involving electrophiles and intramolecular assistance by nucleophiles Allan J. Canty, Gerard van Koten Accounts of Chemical Research Molecular SciencesEngineeringBiochemistryNatural SciencesElectrosynthesis	1995	223
Palladium‐Catalyzed CH Activation of<i>tert</i>‐Butyl Groups: A Simple Synthesis of 1,2‐Dihydrocyclobutabenzene Derivatives Gerald Dyker Angewandte Chemie International Edition in English	1994	201
A New Route to Fused Aromatic Compounds by Using a Palladium-Catalyzed Alkylation – Alkenylation Sequence Mark Lautens, Sandrine Piguel Angewandte Chemie Chemical EngineeringCross-coupling ReactionDerivativesEngineeringAromatic Compounds	2000	182
Palladacycles as Intermediates for Selective Dialkylation of Arenes and Subsequent Fragmentation Marta Catellani, Maria Chiara Fagnola Angewandte Chemie International Edition in English Selective DialkylationEngineeringPhysicsPdiv IntermediatesNatural Sciences	1995	145
Reactions of Electron-Rich Arylpalladium Complexes with Olefins. Origin of the Chelate Effect in Vinylation Catalysis Moshe Portnoy, Yehoshoa Ben‐David, Itay Rousso, Organometallics Chemical EngineeringVinylation CatalysisEngineeringCross-coupling ReactionBiochemistry	1994	131
Cleavage of Palladium Metallacycles by Acids: A Probe for the Study of the Cyclometalation Reaction Juan Cámpora, Jorge A. López, Pilar Palma, Angewandte Chemie International Edition Inorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringHeterocyclic	1999	122
A catalytic process based on sequential ortho-alkylation and vinylation of ortho-alkylaryl iodides via palladacycles Marta Catellani, Federica Cugini Tetrahedron Chemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisOrtho-alkylaryl Iodides	1999	104

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