High-Efficiency Cu₂O-Based Heterojunction Solar Cells Fabricated Using a Ga₂O₃Thin Film as N-Type Layer

Abstract

High-efficiency heterojunction solar cells consisting of a nondoped Ga2O3 thin film as an n-type semiconductor layer and a p-type Cu2O sheet as the active layer as well as the substrate, prepared by thermally oxidizing a Cu sheet, are demonstrated. The use of an n-type Ga2O3 thin film can greatly improve the performance of n-Ga2O3/p-Cu2O heterojunction solar cells. The highest efficiency of 5.38% was obtained in an Al-doped ZnO/Ga2O3/Cu2O heterojunction solar cell fabricated with an n-Ga2O3 thin-film layer prepared at room temperature with a thickness of 75 nm by a pulsed laser deposition method.