Physical Review Letters · 2013 · 56 citations · 27 references
Natural SciencesChemical EngineeringPattern FormationPhysical ChemistryStochastic ProcessesPrecipitationPrecipitation FormationPrecipitation PhysicsPrecipitation ProcessesReaction-diffusion SystemsConcentrationFront Formation DynamicsPrecipitation Formation MechanismsPrecipitation KineticsReaction FrontsReaction-diffusion Pattern FormationReaction-diffusion Stochastic ModelsSpatiotemporal Pattern Formation
Helical and helicoidal precipitation patterns emerging in the wake of reaction-diffusion fronts are studied. In our experiments, these chiral structures arise with well-defined probabilities P(H) controlled by conditions such as, e.g., the initial concentration of the reagents. We develop a model which describes the observed experimental trends. The results suggest that P(H) is determined by a delicate interplay among the time and length scales related to the front and to the unstable precipitation modes and, furthermore, that the noise amplitude also plays a quantifiable role.
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