[1,3]-Sigmatropic shifts of alkoxides

[3,3]Sigmatropic rearrangements of 1,5-diene alkoxides. Powerful accelerating effects of the alkoxide substituent

David A. Evans, A. M. Golob · Journal of the American Chemical Society · 1975 · 320 citations

Natural Sciences, Chemistry, Analytical Chemistry +6

Reaction of crotylmagnesium bromide with hindered ketones, First examples of the reversible Grignard reaction

Robert A. Benkeser, William E. Broxterman · Journal of the American Chemical Society · 1969 · 46 citations

Natural Sciences, Chemistry, Chemical Kinetics +5

The first documented reversible addition of allylmagnesium bromide to a ketone

Robert A. Benkeser, Michael P. Siklosi · The Journal of Organic Chemistry · 1976 · 25 citations

Natural Sciences, Chemistry, Analytical Chemistry +4

SOME REARRANGEMENT REACTIONS OF BENZYLMAGNESIUM CHLORIDE

Henry Gilman, James E. Kirby · Journal of the American Chemical Society · 1932 · 19 citations

Natural Sciences, Chemistry, Analytical Chemistry +6

Unusually fast [1,3] sigmatropic shifts

Richard W. Thies, E. Philip Seitz · Journal of the Chemical Society Chemical Communications · 1976 · 18 citations

Natural Sciences, Chemistry, Organic Chemistry +5