Concepedia

Asymmetric Simmons−Smith Cyclopropanation of Unfunctionalized Olefins

Journal of the American Chemical Society · 2003 · 90 citations · 12 references

Abstract

This paper describes a promising asymmetric cyclopropanation system for unfunctionalized olefins using readily available dipeptide N-Boc-l-Val-l-Pro-OMe as ligand.

References

12

A NEW SYNTHESIS OF CYCLOPROPANES FROM OLEFINS

Howard E. Simmons, Ronald D. Smith · Journal of the American Chemical Society · 1958 · 653 citations

Molecular Sciences, Heterocyclic, Alkene Metathesis +9

The Cyclopropyl Group in Studies of Enzyme Mechanism and Inhibition

Colin J. Suckling · Angewandte Chemie International Edition in English · 1988 · 177 citations

Biosynthesis, Engineering, Cyclopropyl Group +11

Exploring new reactive species for cyclopropanation

Zhiqiang Yang, Jon C. Lorenz, Yian Shi · Tetrahedron Letters · 1998 · 162 citations

Heterocyclic, Engineering, Organic Chemistry +3

Asymmetric cyclopropanation of 1-alkenylboronic esters and its application to the synthesis of optically active cyclopropanols

Toshiro Imai, Hiroshi Mineta, Shinya Nishida · The Journal of Organic Chemistry · 1990 · 133 citations

Asymmetric Cyclopropanation, Engineering, Heterocyclic +13

An asymmetric Simmons-Smith reaction

Isao Arai, Atsunori Mori, Hisashi Yamamoto · Journal of the American Chemical Society · 1985 · 119 citations

Quantitative Methods, Databases, Media Standards +17