Chiral magnetic metal–organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

Xiao‐Lan Tong, Tong‐Liang Hu, Jiong‐Peng Zhao, Yuekui Wang, Hui Zhang, Xian‐He Bu

Chemical Communications · 2010 · 138 citations · 29 references

Concepts

Abstract

The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.

References

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