Journal of the Chemical Society Dalton Transactions · 1998 · 21 citations · 14 references
Natural SciencesBiochemistryChemistryCatalysisChemical KineticsInorganic ChemistryCatalytic MechanismsChemical Reaction KineticsEnzyme KineticsLanthanide ChemistryPka DeterminationCatalysis Of Phosphodiester ReactionsHydrolysisLanthanide CatalysisLanthanide KineticsPh DependencePh Dependence Of CatalysisPh Dependence Of HydrolysisPhosphodiester Bond Hydrolysis Kinetics
Lanthanide(III) cations in aqueous Bis-tris propane buffer remained stable at elevated pH values and at pH 9.0 catalyzed the hydrolysis of several phosphodiester substrates 103 times more efficiently than in neutral solutions.
14
Janet R. Morrow, Lisa A. Buttrey, Valerie M. Shelton et al. · Journal of the American Chemical Society · 1992 · 267 citations