Kinetics of phosphodiester hydrolysis by lanthanide ions in weakly basic solutions

Paola Gómez-Tagle, Anatoly K. Yatsimirsky

Journal of the Chemical Society Dalton Transactions · 1998 · 21 citations · 14 references

Concepts

Abstract

Lanthanide(III) cations in aqueous Bis-tris propane buffer remained stable at elevated pH values and at pH 9.0 catalyzed the hydrolysis of several phosphodiester substrates 103 times more efficiently than in neutral solutions.

References

14