Physical Review Letters · 1981 · 655 citations · 9 references
Natural SciencesPhysicsCondensed Matter PhysicsQuantum MechanicsThermodynamicsMetastable PhasesQuantum TunnelingSecond Law Of ThermodynamicsStatistical MechanicsStatistical ThermodynamicsThermodynamic StabilityMetastable RegionMetastable State ThermodynamicsMetastable StatesNonequilibrium Quantum Statistical MechanicsQuantum Mechanical TunnelingQuantum Tunneling EffectsSaddle Point ProblemsTemperature Dependence Of Tunneling
Consider a system rendered unstable by both quantum tunneling and thermodynamic fluctuation. The tunneling rate $\ensuremath{\Gamma}$, at temperature ${\ensuremath{\beta}}^{\ensuremath{-}1}$, is related to the free energy $F$ by $\ensuremath{\Gamma}=(\frac{2}{\ensuremath{\hbar}})\mathrm{Im}F$. However, the classical escape rate is $\ensuremath{\Gamma}=(\frac{\ensuremath{\omega}\ensuremath{\beta}}{\ensuremath{\pi}})\mathrm{Im}F$, $\ensuremath{-}{\ensuremath{\omega}}^{2}$ being the negative eigenvalue at the saddle point. A general theory of metastability is constructed in which these formulas are true for temperatures, respectively, below and above $\frac{\ensuremath{\omega}\ensuremath{\hbar}}{2\ensuremath{\pi}}$ with a narrow transition region of $O({\ensuremath{\hbar}}^{\frac{3}{2}})$.
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Statistical theory of the decay of metastable states
J. S. Langer · Annals of Physics · 1969 · 1.4K citations
Theory of the condensation point
J. S. Langer · Annals of Physics · 1967 · 1.3K citations