Analysis of Crystal Structure of an Y-Ba-Cu Oxide

Yasuyuki Kitano, Kouichi Kifune, Ichiro Mukouda, H. Kamimura, J. Sakurai, Y. Komura, Kenichi Hoshino, Morihisa Suzuki, Asao Minami, Y. Maeno,

Japanese Journal of Applied Physics · 1987 · 18 citations · 3 references

Concepts

Abstract

Results of the analyses on crystal structure and chemical composition of dark-green crystals mainly found in an Y-Ba-Cu oxide specimen which shows high- T c superconductivity are reported. Crystal structure is investigated by the electron diffraction method and is determined to be orthorhombic with lattice parameters a =1.22 nm, b =0.561 nm and c =0.714nm, and with a space group Pnma (No. 62) or Pna2 1 (No. 33). Expected d -values are presented and are successfully compared with the X-ray powder diffraction spectrum obtained from this oxide. Chemical composition is analyzed by the EPMA method and is determined to be Y 2 BaCuO 5- y for the oxide.

References

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