Hyperconjugation: An alternative to the concept of the pπ–dπ bond in Group IV chemistry

An Algorithm for Least-Squares Estimation of Nonlinear Parameters

Donald W. Marquardt · Journal of the Society for Industrial and Applied Mathematics · 1963 · 30.4K citations

Natural Sciences, Computational Engineering, Optimization +11

Formulas and Numerical Tables for Overlap Integrals

Robert S. Mulliken, Carol A. Rieke, D. Orloff et al. · The Journal of Chemical Physics · 1949 · 950 citations

Natural Sciences, Chemistry, Physics +15

Band Shapes of the Electronic Spectra of Complex Molecules

Donald B. Siano, David E. Metzler · The Journal of Chemical Physics · 1969 · 394 citations

Natural Sciences, Chemistry, Spectroscopic Analysis +13

Cyanocarbon Chemistry. II.¹ Spectroscopic Studies of the Molecular Complexes of Tetracyanoethylene

R. E. Merrifield, William D. Phillips · Journal of the American Chemical Society · 1958 · 336 citations

Natural Sciences, Chemistry, Organic Chemistry +6

Modes of carbonium ion stabilization. Evidence from charge-transfer spectra

Walter G. Hanstein, Harvey J. Berwin, T. G. TRAYLOR · Journal of the American Chemical Society · 1970 · 158 citations

Natural Sciences, Chemistry, Inorganic Chemistry +6