Photocapacitance of Nanocrystalline Oxide Semiconductor Films:  Band-Edge Movement in Mesoporous TiO₂ Electrodes during UV Illumination

Abstract

Impedance measurements of mesoporous TiO 2 electrodes in contact with aqueous and nonaqueous electrolytes have been performed in the dark and under UV illumination. In the dark the differential capacitance was found to be dominated by the back contact. Bandgap excitation of the TiO 2 film turned on a capacitance associated with the mesoporous semiconductor layer. This is interpreted in terms of trapping of photogenerated holes in surface states leading to unpinning of the energy bands. The unpinning of the energy bands during UV illumination was confirmed by a dye-sensitization experiment.