Concepedia

Cation radical-induced Claisen rearrangement of aryl allenylmethyl ethers

C.S. Venkatachalam, K. K. BALASUBRAMANIAN

Journal of the Chemical Society Chemical Communications · 1994 · 11 citations · 13 references

DOI

Concepts

Abstract

Treatment of aryl allenylmethyl ethers with tris(4-bromophenyl)aminium hexachloroantimonate in acetonitrile at room temperature induces a facile cation radical induced Claisen rearrangement to yield 2-(o-hydroxyaryl)buta-1,3-dienes.

References

13

Application of commercial microwave ovens to organic synthesis.

R. J. GIGUERE, Terry Bray, Scott M. Duncan et al. · Tetrahedron Letters · 1986 · 1.1K citations

, , +6

Cation radical cycloadditions and related sigmatropic reactions

Nathan L. Bauld · Tetrahedron · 1989 · 307 citations

, , +8

Cation radical pericyclic reactions

Nathan L. Bauld, Dennis J. Bellville, B. HARIRCHIAN et al. · Accounts of Chemical Research · 1987 · 229 citations

, , +8

Mechanistic diagnosis of aminium salt initiated Diels-Alder cycloadditions in the diene/diene format

Dan W. Reynolds, Kurt Lorenz, Huh Sun Chiou et al. · Journal of the American Chemical Society · 1987 · 72 citations

, , +4

Photochemical para Rearrangement of Phenyl Ethers

M. S. Kharasch, Guido Stampa, W. Nudenberg · Science · 1952 · 69 citations

, , +10