Concepedia

Tungsten carbonyl precursors in catalyzed olefin metathesis. III. infrared study of R<sub>n</sub>Cl<sub>3‐n</sub>SnW(CO)<sub>3π</sub>−C<sub>5</sub>H<sub>5</sub>derivatives and their interaction with iBuAlCl<sub>2</sub>and O<sub>2</sub>

L. M. Vanderyse, Timothy Haemers, A.R. Bossuyt, L. Verdonck, G.P. Van Der Kelen

Bulletin des Sociétés Chimiques Belges · 1988 · 10 citations · 16 references

DOI

Abstract

Abstract The LW(CO) 3 Cp (L = R n SnCl 3‐n , H, Cl) derivatives and their interaction with iBuAlCl 2 and O 2 have been studied by i. r. spectroscopy. Mechanisms for the generation of the active tungsten‐carbene complex in the early stages of reaction are proposed.

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