Palladium supported on natural phosphate: Catalyst for Suzuki coupling reactions in water

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides

Richard F. Heck, J. P. Nolley · The Journal of Organic Chemistry · 1972 · 2.1K citations

Chemical Engineering, Cross-coupling Reaction, Engineering +12

The Palladium-Catalyzed Cross-Coupling Reaction of Phenylboronic Acid with Haloarenes in the Presence of Bases

Norio Miyaura, Teiji Yanagi, Atsushi Suzuki · Synthetic Communications · 1981 · 1.9K citations · Full text

Transition Metal-catalyzed Reactions, Chemical Engineering, Cross-coupling Reaction +11

Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions

Adam F. Littke, Chaoyang Dai, Gregory C. Fu · Journal of the American Chemical Society · 2000 · 1.6K citations

Arylboronic Acids, Chemical Engineering, Cross-coupling Reaction +13

Highly Active Palladium Catalysts for Suzuki Coupling Reactions

John P. Wolfe, Robert A. Singer, Bryant H. Yang et al. · Journal of the American Chemical Society · 1999 · 1.1K citations

Chemical Engineering, Cross-coupling Reaction, Engineering +9