Concepedia

Dimerization of the Trinuclear Mercury(II) Complex [(<i>o</i>-C<sub>6</sub>F<sub>4</sub>Hg)<sub>3</sub>·<i>μ</i><sub>3</sub>-acetone] via Mercurophilic Interactions

J.B. King, M.R. Haneline, M. Tsunoda, François P. Gabbaı̈

Journal of the American Chemical Society · 2002 · 93 citations · 11 references

DOI

Concepts

Abstract

In the crystalline state, the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)*mu(3)-acetone] forms cofacial dimers which are held by two mercurophilic interactions of 3.51 A. In this form, the complex displays an intense photoluminescence with a sharp emission centered at 480 nm.

References

11

The fascinating implications of new results in gold chemistry

Hubert Schmidbaur · Gold bulletin · 1990 · 587 citations

, , +4

A revision of van der Waals atomic radii for molecular crystals: N, O, F, S, Cl, Se, Br and I bonded to carbon

S. C. Nyburg, Carlos H. Faerman · Acta Crystallographica Section B Structural Science · 1985 · 515 citations

, , +14

Solvent‐Stimulated Luminescence from the Supramolecular Aggregation of a Trinuclear Gold(<scp>I</scp>) Complex that Displays Extensive Intermolecular AuċAu Interactions

Jess C. Vickery, Marilyn M. Olmstead, Ella Y. Fung et al. · Angewandte Chemie International Edition in English · 1997 · 384 citations

, , +21

Synthesis, structure, and electronic spectroscopy of neutral, dinuclear gold(I) complexes. Gold(I)-gold(I) interactions in solution and in the solid state

Ratnavathany Narayanaswamy, Michelle Young, Erica Parkhurst et al. · Inorganic Chemistry · 1993 · 208 citations

, , +13

π-Complexation of Biphenyl, Naphthalene, and Triphenylene to Trimeric Perfluoro-<i>ortho</i>-phenylene Mercury. Formation of Extended Binary Stacks with Unusual Luminescent Properties

M.R. Haneline, M. Tsunoda, François P. Gabbaı̈ · Journal of the American Chemical Society · 2002 · 180 citations

, , +12