Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

Emmanuel Callens, Edy Abou‐Hamad, Nassima Riache, Jean‐Marie Basset

Chemical Communications · 2014 · 19 citations · 31 references

Concepts

Abstract

Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin.

References

31