Journal of Thermophysics and Heat Transfer · 2000 · 25 citations · 22 references
EngineeringDifferential Scanning CalorimetryFluid MechanicsExperimental ThermodynamicsOptical DiagnosticsGas DynamicNumerical SimulationThermodynamicsBiophysicsLaser-induced Fluorescence SpectroscopyPhysicsLaser SpectroscopyLaser-induced E UorescenceLaser PhotochemistryNatural SciencesSpectroscopyLaser-induced BreakdownApplied PhysicsTemperature MeasurementE OwBlunt BodySpectroscopic Method
The e owe eld generated by the high-enthalpy arcjet facility L2K, simulating the stagnation conditions during shuttlereentry and mainly used for testing thermal protection materials, is investigated by using the laser-induced e uorescence (LIF)diagnostictechnique.FortheoperationconditionsoftheL2KfacilityofDLR,thee owconditions are dominated by nonequilibrium effects. In particular, translational and rotational temperatures are assumed to beinequilibrium,butlargedifferencesbetweenrotational,vibrational,and electronictemperatureoccur.Spatially resolved LIF is used to determine rotational and translational temperature of NO molecules and O atoms in the freestream and behind a bow shock upstream of a blunt body. The e ow is modeled numerically using a quasione-dimensional code and a full Navier ‐Stokes two-dimensional axisymmetric code. Good agreement is achieved between the experimental and numerical data in the freestream. The data are also compared with the coherent Stokes anti-Raman scattering measurements performed previously at the same e ow conditions in the same facility on the N2 molecules. Differences caused by the nonequilibrium aspects, in the freestream and across the shock layer, of N2, NO, and O components are evident, and the physical interpretation is discussed.
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Photochemistry of small molecules
Richard P. Wayne · Nature · 1979 · 709 citations
Photochemistry, Natural Sciences, Mechanistic Photochemistry +3