Acta Crystallographica Section C Crystal Structure Communications · 1995 · 10 citations · 0 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryPhysical ChemistryCrystal ChemistryCrystal SymmetryCrystallographyStructure DeterminationX-ray CrystallographyX-ray DiffractionCrystal Structure DeterminationCrystal Structure RefinementCrystal Symmetry DeterminationCrystallographic CharacterizationNickel ChemistrySingle-crystal X-ray Diffraction
The crystal structure of the α form of bis(N,N-diethyldithiocarbamato-S,S')nickel(II), [Ni(C 5 H 10 NS 2 ) 2 ], has been redetermined at 290 K by single-crystal X-ray methods. The Ni atom assumes a four-coordinate square-planar geometry with two isobidentate dithiocarbamate groups. The results confirm those of a previous study [Bonamico, Dessy, Mariani, Vaciago & Zambonelli (1965). Acta Cryst. 19, 619-627] but are more precise